Book Description
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. The treatment emphasizes unifying principles, showing how common mechanisms link seemingly disparate reactions. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.
The author has drawn on his own research and the current literature to ensure that appropriate attention is given to topics across the range of modern organic chemistry. The text is unique in its inclusion of a chapter on reactions mediated or catalyzed by transition metals, an area in which mechanistic understanding is now essential. Relatively new topics such as olefin metathesis and cycloaromatization are covered without giving short shrift to more traditional areas such as carbonyl chemistry. The text assumes a basic knowledge of organic chemistry. It can be used either in a formal course or by students working on their own, and will be particularly useful for graduate students studying for qualifying examinations. It will also be useful to students and researchers in biochemistry, pharmacology, and inorganic chemistry.
"This is an excellent and well-presented work.... The author ... has succeeded well in treating the central ideas of reactivity and selectivity in an integrated whole. The clear style of writing, the well chosen examples, and the ... concise summaries of the main points provided at the end of each chapter should enable the reader to easily consolidate what has been learned.... The book is indeed a little work of art."
-- Jens Hartung, Angewandte Chemie International Edition
"I have taught a one-credit course with this book for three years, and, uniformly, the students have rated this book highly for its clarity and for the scope of the problems. ... This book does an excellent job at its stated goal: 'to teach students to come up with reasonable mechanisms for reactions they have never seen before.'"
-- Amy Howell, Synthesis
"I have just finished my first year of graduate studies in organic chemistry at Duke University. I just wanted to let you know how much your book got me through the past year of course work.... When it came to mechanisms, I found the clarity and thoroughness I needed only in your book. It was impressive how you were able to present so much information in a clear and comprehensive manner yet keep the book so manageable in size. In addition to the text, I also was able to benefit from the problems.... Great practice!! The on-line answers are much better than looking up answers by reference.... I am reading it again this summer in preparation for my preliminary exam next spring."
-- David Gooden
Customer Reviews:
basics for organic chemist.......2007-05-10
This book is excellent for reaction mechanism. This book is helpful for the undergraduate's organic chem 2 and the grad school's reaction mechanism class. I learned how to move the electron in reasonable way. So in one word, this book is awesome book that I ever read for practicing reaction mechanism.
Excellent Book on Mechanisms.......2006-11-04
I bought this book to practice mechanisms because I'll be taking a physical organic class in the spring that uses them heavily. I used this book instead of sitting in on a sophomore organic class, because by job as a TA conflicted.
Anyway, this book is extraordinary. Dr. Grossman has taught me so many things about how to write a correct mechanism and how to recognize a bad mechanism when I see one. The book is written in a very clear and friendly manner and it's really quite hard to put down when you start reading it.
The book also has practice problems and the book's website has the answers, giving even more incentive to practice mechanisms.
Money well spent........2006-03-21
This compact but content-rich book is ideal for students who have completed at least their first year of organic chemistry (some physical chemistry is helpful but not critical) and wish to improve their understanding of the subject. The writing style is generally remarkably clear and readable; the author manages to make an inherently intimidating subject surprisingly easy to approach and understand.
I would recommend it to any student of chemistry, regardless of whether it fits into your scheduled courses.
Orgo Made Easy!.......2005-09-30
This book is a condensed version of my text book. With this book, GOD and "Orgo for dummies", I aced Organic the first time through.
Surprisingly Easy to Read and Understand.......2005-09-04
Being a PhD student in organic chemistry, I have read a lot of chemistry books in my days, and never have I come across a book that's understandable without a teacher's explanation. The numerous examples and pictures makes understanding what the author is writing about a breeze. I would highly suggest this book to anyone who is looking into pursuing a degree in Chemistry. It has already helped me out a great deal and I'm barely half way through!
Book Description
The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions.
The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease.
New features include:
- More than 25,000 references to the literature to facilitate further research
- Revised mechanisms, where required, that explain concepts in clear modern terms
- Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries
- A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
Customer Reviews:
Pleased.......2007-09-27
The book arrived on time and in the condition indicated. Pleasure to do business with.
eh.......2007-08-31
i always thought this book was overrated. it's just not a text you can sit down, relax, and enjoy. it's definitely a reference text, and for a reference text, it's definitely not the first one I go to.
6th March is an excellent buy.......2007-08-08
It is very difficult to rewrite reviews for 6th edition of the "March". Classical flagships among textbooks and reference books in organic chemistry, unbeatable. With 7000 new refernces it brings unbelievable 25k reference citations, very well organized on the bottom of the pages. Excellent indexes, very good cross view between 5th edition and 6th edition aligning chapters of different numbering, perfect drawings made in CamSoft ChemDraw, etc. etc. As the text and accompanying material is polished and polished edition to edition, it is very difficult to do anything else but to praise this excellent reference book, which hardly could be omitted in any chemical laboratory. Not only that but hardcover book of 2357 pages for $73 at Amazon is not only a good book but also a good buy.
very fast shipping and very good conditions of the book.......2007-05-13
very fast shipping and very good conditions of the book
Good oganic chemistry.......2007-03-22
As for the 5th edition this new one is really clear and fully of bibliografic reference. I really appreciate that, now, the references are below at the page and not at the end of the chapter, form me this change help to finding the information. I think that this is one of the most complete book for the organic chemist.
Book Description
From the reviews of the Fourth Edition ...
"March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education
"The ratio of information to price makes this book a wonderful bargain."-American Scientist
New to this Fifth Edition:
* Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition
* Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition
* 40 entirely new sections covering the most important developments in organic chemistry since the previous edition
* Updated illustrations of molecular structures
Customer Reviews:
Nice book, for sure.......2006-11-06
I'm pretty sure that you _must_ have this book if you are studying advanced organic chemistry. Maybe it's not the best one to use as a study guide, but it's extremely helpful as a reference book both for undergrads and graduate students. However, one can argue that this edition is a bit out-of-date.
The Best Reference for Organic Chemistry.......2005-10-09
This is by far the best text I have found. Although it is considered a text book, it is more handy as a reference tool. I have seen no other book that contains more information than March's. This book is actually worth the price.
An investment that'll last you for years........2004-09-04
I bought a copy of this text (2nd Ed) after finishing my sophomore year of college, and it proved to be the best single investment I've ever made in chemistry. I used it so often, I had to duct-tape the book together.
I think the happiest moment of my career was when my name appeared in the index of a later edition. Anyway, buy it and treasure it.
The Green Bible of Organic Chemistry.......2004-08-15
March never leaves my desk. It covers everything. From functional group transformations to mechanisms to FMO theory - you name it it's there. Highly recommended for any advanced undergraduate, graduate or post-doctoral researcher. It's a bookshelf staple that any organic chemist should have available.
1495 Page Bible Of General Reactions And Mechanisms.......2004-02-09
I paid more for my 4th ed. new, and find it to be worth even more. It is not a cookbook per se, but it is a very comprehensive textbook that details general reactions by functional group. It outlines every way known to remove, add to, or otherwise modify every functional group. There is as much commentary as is needed, if not more, and every pathway is mentioned regardless of how exotic or primitive and low-yielding. The corresponding OS synth refs for specific cpds. are given for each type of reaction, along with a total of 15,000 other refs in footnotes. This was cutting-edge in 92, with much updating of the 3rd ed. The index will take you to the section that shows how to make the manipulations you want - if it doesn't, it probably can't be done.
Average customer rating:
- A lot of problems will be solved in later revisions
- Professor Silverman does it again!
|
Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition, Second Edition
Richard B. Silverman
Manufacturer: Academic Press
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ASIN: 0126437319 |
Book Description
The Organic Chemistry of Enzyme-Catalyzed Reactions is not a book on enzymes, but rather a book on the general mechanisms involved in chemical reactions involving enzymes. An enzyme is a protein molecule in a plant or animal that causes specific reactions without itself being permanently altered or destroyed.
This is a revised edition of a very successful book, which appeals to both academic and industrial markets.
Illustrates the organic mechanism associated with each enzyme-catalyzed reaction
Makes the connection between organic reaction mechanisms and enzyme mechanisms
Compiles the latest information about molecular mechanisms of enzyme reactions
Accompanied by clearly drawn structures, schemes, and figures
Includes an extensive bibliography on enzyme mechanisms covering the last 30 years
Explains how enzymes can accelerate the rates of chemical reactions with high specificity
Provides approaches to the design of inhibitors of enzyme-catalyzed reactions
Categorizes the cofactors that are appropriate for catalyzing different classes of reactions
Shows how chemical enzyme models are used for mechanistic studies
Describes catalytic antibody design and mechanism
Includes problem sets and solutions for each chapter
Written in an informal and didactic style
Customer Reviews:
A lot of problems will be solved in later revisions.......2003-05-05
The index for this book .... For example, there are a fair number of examples of the epoxidation reaction, but not a single pointer toward that in the index of the book. And much the same thing for other types of reactions.
It would also be nice if there was a more clear transfer between basic organic principles and then biological applications.
He does do a good job showing this is some cases (i.e., the benzoin condensation), but a few more parallel examples would have been very useful.
Professor Silverman does it again!.......2000-06-17
This book is an excellent resource for undergraduate and graduate students studying enzyme chemistry and organic mechanisms. Prof. Silverman does a fine job of giving many different examples of enzyme mechanisms. By not focusing totally on one kind of enzyme or catalysis, he succeeds in painting a broad picture for the reader, while not sacrificing content. The only drawback to this edition is the large amount of typographical errors that appear throughout. Perhaps better editing is in order for future editions.
Book Description
A classic textbook on mechanistic organic chemistry which is characterised particularly by its clarity, careful choice of examples and its general approach that is designed to lead to a ready understanding of the subject matter. This guidebook is aimed clearly at the needs of the student, with a thorough understanding of, and provision for, the potential conceptual difficulties he or she is likely to encounter.
Customer Reviews:
This book has good sides and bad sides.......2005-08-26
The book is a condensed source of information of various different subjects relating to organic chemistry. In saying so it is a general overview of practical organic chemistry. Sykes is clear in his explanation and elucidation on various reaction mechanisms and as he states early on, he does promote a mechanistic perspective of organic chemistry.
Sykes is particularly useful for individuals who have done introductory organic chemistry and are venturing into deeper topics of the subject, i.e. stereochemistry and synthesis as examples (a lot of universities offer courses which purely concentrate on these regions of study).
Now the greatest downfall I see about the text is the price. March's advanced organic chemistry is much more extensive, newer and my personal opinion is that the authorship is better in March's
Another downfall is the age, although a lot of the topics that have been introduced in this book have not changed significantly and therefore dont seriously affect the text's validity; I still feel it should have had an update. This book was published in the 1980's (the late era of the decade).
All I am saying is that Syke's book is a classic, one can learn a lot from it and it is a fairly good reference book, however to my understanding there are better texts of the same genre covering practically the same themes as in this book.
I would strongly recommend any individual interested in this book to have a look at March's Advanced Organic Chemistry.
Waste of Money.......2001-07-06
I have read this book. Nothing genuine about this book! The content has no difference than that of any textbooks. I threw this book in the trash can. I don't want to resell it because I don't want to waste other people's money and time.
Valuable Reference for Organic Chemistry.......2000-08-27
Peter Sykes' guidebook formats more as a reference to organic reactions such as nucleophilic substitution, electrophilic substitution, nucleophilic addition to carbonyl, elimination reactions, radical reactions and symmetry-controlled reactions such as pericyclic reactions. It is well written, clear, and succinct that undergraduate and graduate students will welcome it as a companion to an organic course. Sykes also discusses topics that are often omitted in an introductory text such as carbocations, electron-deficient species, carbanions, and linear free energy relationships. It can be thought of a compact version of Jerry March's Advanced Organic Chemistry, which is widely used as a graduate text. As a purchase guideline, I also purchased Hoffman's "Organic Chemistry: An Intermediate Text", and Bernard Miller's "Advanced Organic Chemistry", which treat the subject of electrocyclic reactions and cycloaddition more thoroughly. The portable size of Sykes makes it an excellent source of reference.
Modern classic.......1998-04-11
This book was recommended to me by a senior lecturer in Organic Chemistry at a Scottish university: A very fine example of a British gentleman - and a very good recommendation he made.
I have always prized this book and return to it again and again, although my current scientific work involves little organic chemistry. The presentation is very considerate to beginners and sympathetic of their problems. Even advanced chemists will appreciate its clear and insightful presentation of the logic behind organic reaction mechanisms.
Peter Sykes' book is certainly a model of clarity and to my mind perhaps the best book ever written on this vast subject. It is certainly my favorite organic chemistry book: All the explanations are clear and helpful; one is never (or very rarely) left dangling at the end of a presentation wondering just what in the world is going on, as seems to happen too often in other texts.
Sykes starts at the basic level of structure and reactivity, proceeds to acid/base equilibria, and addresses subsequent chapters to electrophilic, nucleophilic, radical, carbanion/carbocation reactions, Hammett plots, etc.
Really a wonderful read and an outstanding short reference. Certainly an excellent investment for anyone interested in organic chemistry. How odd most Americans are unfamiliar with it.
(If you value Sykes' presentation, the Royal Society of Chemistry used to have several audio cassettes of his presentations on organic chemistry.)
Book Description
Kurti and Czako's
Strategic Applications of Named Reactions in Organic Synthesis: Premium Hardcover Edition with CD-ROM is an indispensable tool for both specialists and non-specialists in the field of organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient two-page layout, using color for the first time in an advanced-level organic chemistry book. Each reaction includes a list of main features, a general scheme of the transformation, and a detailed arrow-pushing mechanism based on the latest experimental evidence. It then provides numerous examples demonstrating the synthetic utility of each reaction followed by a list of references.
This premium hardback edition also includes a CD-ROM that integrates a PDF master page linked via color links to the text pages of the book itself. A user will be able to go from lecture format to the bookpage and back with the click of a mouse.
Together both the CD-ROM and hardback text offers the most comprehensive coverage, superb organization, quality of presentation, and wealth of references for organic chemists everywhere.Due to its comprehensive coverage, superb organization, quality of presentation, and wealth of references, this long-awaited book belongs on the shelf of every organic chemist.
* The first reference work on named reactions to present colored schemes for easier understanding
* 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples
* An opening list of abbreviations includes both structures and chemical names
* Contains more than 10,000 references grouped by seminal paper, reviews, modifications, and theoretical works
* Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools
* Extensive index quickly locates information using words found in text and drawings
Book Description
A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry.Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments.Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.
Book Description
The third edition contains major improvements over the previous edition. In addition to updated references, each reaction is now supplemented with two to three representative examples in synthesis to showcase its synthetic utility. Biographical sketches for the chemists who discovered or developed those name reactions have been included. Furthemore, the subject index is significantly expanded.
Different from other books on name reactions in organic chemistry, Name Reactions, A Collection of Detailed Reaction Mechanisms focuses on their mechanisms. It covers over 300 classical as well as contemporary name reactions. Each reaction is delineated by its detailed step-by-step, electron-pushing mechanism, supplemented with the original and the latest references, especially review articles. Thus, it is not only an indispensable resource for senior undergraduate and graduate students for learning and exams, but also a good reference book for all chemists interested in name reactions.
Some praise for the previous edition:
"This is an excellent book for arrow pushing and learning organic name reactions as encountered in graduate school . . . Li’s book contains reactions of all mechanistic classes . . . The book is nicely balanced, containing modern-day reactions for assembly of stereocomplex molecules. Reactions such as the Corey-Bakshi-Shibata reduction are analyzed. This book is a good reference text that fills a void that has existed for some time. It is both an excellent tool for learning and a good reference source."
Journal of Chemical Education
Customer Reviews:
Awesome book.......2007-05-10
This book is nice for writing the basics of mechanism. There are some other books available in market. But I will recommend this book because they are short and concise. This third edition is more or less similar to second edition.
best name reactions book.......2006-03-23
this book is a really great resource for organic chemists. it has all the main name reactions in alphabetical order, and does a good job showing not only the overall reaction, but also the step-by-step mechanism as well. it also has references listed for each reaction, for further clarification. i recommend it for any organic chemist as part of their library.
The named reactions bible.......2005-08-16
This book is fantastic! It has a complete set of every important named reaction with its respective mechanism and literature references. The simple layout makes this book very user friendly. The mechanisms are easy to follow and the references are very useful making this book excellent for use at any level from undergraduate to graduate and beyond. This book is a definite must have for anyone studying advanced organic chemistry, as it is the named reactions bible.
not bad if you can't write a mechanism..........2005-08-06
Basically, all this book does is draw mechanisms for a whole bunch of name reactions. It doesn't really tell you all that much and only gives one example (for which the mechanism is drawn out)or each. Definately not recomended if you know how to push arrows and write a mechanism. Not at all what I was expecting.
A excellent collection of important Name Reactions.......2004-04-10
This book is a must for any undergrad, graduate student or for that matter, CHEMIST, at any level who is interested in Name Reactions. It contains 331 name reactions that range from classic organic chemistry to modern day organic chemistry. An excellent collection of important name reactions that is in an easy to read format. Each reaction contains a brief summary, a general reaction scheme and a detailed arrow pushing mechanism.
I really like this book because of its contents and simplicity. Its very easy to find the reaction you are looking for and the information is complete. It would be very helpful in studying for advance organic chemistry exams or as a quick reference when you do not know a particular named reaction. The index is about average for this type of book; however, this book is based on the fact that you are looking up named reactions and not using it as a functional group conversion reference.
After all is said and done, I can truly say that I am glad I purchased this book. It is a complete summary of named reactions and I look forward to using it in the years to come.
Thanks
Book Description
Books Dealing with the mechanisms of enzymatic reactions were written a generation ago. They included volumes entitled Bioorganic Mechanisms, I and II by T.C. Bruice and S.J. Benkovic, published in 1965, the volume entitled Catalysis in Chemistry and Enzymology by W.P. Jencks in 1969, and the volume entitled Enzymatic Reaction Mechanisms by C.T. Walsh in 1979. The Walsh book was based on the course taught by W.P. Jencks and R.H. Abeles at Brandeis University in the 1960's and 1970's. By the late 1970's, much more could be included about the structures of enzymes and the kinetics and mechanisms of enzymatic reactions themselves, and less emphasis was placed on chemical models. Walshs book was widely used in courses on enzymatic mechanisms for many years. Much has happened in the field of mechanistic enzymology in the past 15 to 20 years. Walshs book is both out-of-date and out-of-focus in todays world of enzymatic mechanisms. There is no longer a single volume or a small collection of volumes to which students can be directed to obtain a clear understanding of the state of knowledge regarding the chemicals mechanisms by which enzymes catalyze biological reactions. There is no single volume to which medicinal chemists and biotechnologists can refer on the subject of enzymatic mechanisms. Practitioners in the field have recognized a need for a new book on enzymatic mechanisms for more than ten years, and several, including Walsh, have considered undertaking to modernize Walshs book. However, these good intentions have been abandoned for one reason or another. The great size of the knowledge base in mechanistic enzymology has been a deterrent. It seems too large a subject for a single author, and it is difficult for several authors to coordinate their work to mutual satisfaction. This text by Perry A. Frey and Adrian D. Hegeman accomplishes this feat, producing the long-awaited replacement for Walshs classic text.
Book Description
Writing Reaction Mechanisms in Organic Chemistry, Second Edition, is an invaluable guide to charting the movements of atoms and electrons in the reactions of organic molecules. Miller and Solomon illustrate that understanding organic reactions is based on applying general principles rather than the rote memorization of unrelated processes, and, in turn, emphasize that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. Students and research chemists alike will find this book useful in providing a method of organizing and synthesizing an oftentimes overwhelming quantity of information into a set of general principles and guidelines for determining and describing organic reaction mechanisms.
* Essential for those students who need to have mechanisms explained in greater detail than most organic chemistry textbooks provide.
* Illustrated with hundreds of chemical structures
* Extensively rewritten and reorganized to make the presentation and format even easier for students to use
* Contains many problem sets and answers to all problems to help students work through general principles and applications
* Appendixes have been added to this edition that contain easily referenced information on Lewis structures, symbols for chemical notation, and the relative acidities of common substances
Customer Reviews:
A big step towards the understanding of organic chemistry.......2000-02-04
This book is made for those who think that Organic Chemistry is just a succession of empirical reactions. If you have problems memorizing your Organic course this book should help a lot. All along the text you will learn how to derive a plausible mechanism for a given reaction. Miller did a great job in demonstrating that there is logic in Organic Chemistry. Moreover the book provides solid tools for those who plan to move towards more advanced concepts. This second edition displays a much improved presentation. A must, affordable, simple and efficient.
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