Metal Nanoparticles: Synthesis Characterization & Applications

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A state-of-the-art reference, Metal Nanoparticles offers the latest research on the synthesis, characterization, and applications of nanoparticles. Following an introduction of structural, optical, electronic, and electrochemical properties of nanoparticles, the book elaborates on nanoclusters, hyper-Raleigh scattering, nanoarrays, and several applications including single electron devices, chemical sensors, biomolecule sensors, and DNA detection. The text emphasizes how size, shape, and surface chemistry affect particle performance throughout. Topics include synthesis and formation of nanoclusters, nanosphere lithography, modeling of nanoparticle optical properties, and biomolecule sensors.

Optical Properties of Metal Clusters (Springer Series in Materials Science)

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Optical Properties of Metal Clusters (Springer Series in Materials Science)
Uwe Kreibig , and Michael Vollmer
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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ASIN: 3540578366

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Optical Properties of Metal Clusters deals with the electronic structure of metal clusters determined optically. Clusters - as state intermediate between molecules and the extended solid - are important in many areas, e.g. in air pollution, interstellar matter, clay minerals, photography, heterogeneous catalysis, quantum dots, and virus crystals. This book extends the approaches of optical molecular and solid-state methods to clusters, revealing how their optical properties evolve as a function of size. Cluster matter, i.e. extended systems of many clusters - the most frequently occuring form - is also treated. The combination of reviews of experimental techniques, lists of results and detailed descriptions of selected experiments will appeal to experts, newcomers and graduate students in this expanding field.

Clusters of Atoms and Molecules II: Solvation and Chemistry of Free Clusters, and Embedded, Supported and Compressed Clusters (Springer Series in Chemical Physics)

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Clusters of Atoms and Molecules II: Solvation and Chemistry of Free Clusters, and Embedded, Supported and Compressed Clusters (Springer Series in Chemical Physics)

Manufacturer: Springer
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Binding: Hardcover

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Transition Metal Carbonyl Cluster Chemistry (Advanced Chemistry Texts, Volume 2)

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Transition Metal Carbonyl Cluster Chemistry (Advanced Chemistry Texts, Volume 2)
Paul J. Dyson , and J. Scott McIndoe
Manufacturer: CRC
ProductGroup: Book
Binding: Hardcover

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ASIN: 9056992899

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Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Mesoscopic Materials and Clusters: Their Physical and Chemical Properties (Springer Series in Cluster Physics)

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Mesoscopic Materials and Clusters: Their Physical and Chemical Properties (Springer Series in Cluster Physics)

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Binding: Hardcover

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ASIN: 3540648844

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Mesoscopic physics is a fast growing discipline with countless potential applications. Understanding the science of mesoscopic materials with unique physical and chemical properties is important for the design of nanodevices and materials with unique properties. Clusters as mesoscopic particles represent an intermediate state of matter between single atoms and solid material. This book deals with the properties of clusters in matrixes, on surfaces, and in vacuum. The formation and application of cluster-based materials is discussed. This book will appeal to physicists, chemists, materials researchers, and advanced students.

Cluster Molecules of the p-Block Elements (Oxford Chemistry Primers, No 14)

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Not the right author...

Cluster Molecules of the p-Block Elements (Oxford Chemistry Primers, No 14)
Catherine E. Housecroft
Manufacturer: Oxford University Press, USA
ProductGroup: Book
Binding: Paperback

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ASIN: 0198556985

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This new addition to the successful Oxford Chemistry Primers series provides a comprehensive survey of the structures, bonding, synthesis, and reactivity of the title molecules and includes clusters found in the elemental state as well as compounds. It is the first undergraduate text to include fullerenes C60. Also presented is a balanced introduction to the chemistry and structures of boranes, heterboranes, cubanes, adamantane-type clusters, Zintl ion, donor-acceptor clusters, and others. Terms commonly encountered in cluster chemistry are defined and polyhedral frameworks are described.

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Not the right author..........2001-09-22

This should have been an immensly interesting chapter in inorganic chemistry. But the author doesn't manage to deliver any overview, insight or 'mental discoveries' of new or old concepts. It becomes too much like listening to someone reading from a catalogue.
I appologice, this could have been written in a better way.

Metal-Metal Bonded Carbonyl Dimers and Clusters (Oxford Chemistry Primers, 44)

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Metal-Metal Bonded Carbonyl Dimers and Clusters (Oxford Chemistry Primers, 44)
Catherine E. Housecroft
Manufacturer: Oxford University Press, USA
ProductGroup: Book
Binding: Paperback

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Book Description

The potential commercial uses of some compounds as catalysts has generated much research interest. Metal-metal bonded dimers and clusters are an example of these. This concise basic approach to the subject covers among other topics: structure of metal-metal bonded dimers and clusters including both small and large clusters, synthesis of reprensentative dimers and clusters, and localized bonding schemes and their limitations. Highly illustrated, with a relatively basic text that includes problems, this addition to the Oxford Chemistry Primers series will be valuable to the advanced chemistry undergraduate.

Advances in Metal and Semiconductor Clusters, Volume 4 (Advances in Metal and Semiconductor Clusters)

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Advances in Metal and Semiconductor Clusters, Volume 4 (Advances in Metal and Semiconductor Clusters)
M.A. Duncan
Manufacturer: JAI Press
ProductGroup: Book
Binding: Hardcover

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ASIN: 0762300582

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Cluster Materials is the fourth volume of the highly successful series Advances in Metal and Semiconductor Clusters. In this volume the focus is on the properties of clusters which determine their potential applications as new materials. Metal and semiconductor clusters have been proposed as precursors for materials or as actual materials since the earliest days of cluster research. In the last few years, a variety of techniques have made it possible to produce clusters in sizes varying from a few atoms up to several thousand atoms. While some measurements are performed in the gas phase on non-isolated clusters, many cluster materials can now be isolated in macroscopic quantities and more convenient studies of their properties become possible.

In this volume the authors focus on measurement of optical, electronic, magnetic, chemical and mechanical properties of clusters or of cluster assemblies. All of these properties must fall into acceptable ranges of behaviour before useful materials composed of clusters can be put into practical applications. As evidenced by the various work described here, the realisation of practical products based on cluster materials seems to be approaching rapidly.

Advances in Metal and Semiconductor Clusters, Volume 5 (Advances in Metal and Semiconductor Clusters)

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Advances in Metal and Semiconductor Clusters, Volume 5 (Advances in Metal and Semiconductor Clusters)
M.A. Duncan
Manufacturer: Elsevier Science
ProductGroup: Book
Binding: Hardcover

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ASIN: 0444507264

Book Description

In previous volumes in this series, Advances in Metal and Semiconductor Clusters, the focus has been on atomic clusters of metals, semiconductors and carbon. Fundamental gas phase studies have been surveyed, and most recently scientists have explored new materials which can be produced from clusters or cluster precursors. In this latest volume, the focus shifts to clusters composed primarily of non-metal molecules or atoms which have one or more metal atoms seeded into the cluster as an impurity. These clusters provide model systems for metal ion solvation processes and metal-ligand interactions.
Metal-ligand bonding underlies the vast fields of organometallic chemistry, transition metal chemistry and homogeneous catalysis. Catalytic activity, ligand displacement reactions and photochemical activity depend on the specific details of metal-ligand bonding. Likewise, metal ions are ubiquitous in chemistry and biology and weaker electrostatic interactions play a leading role in their function. In solution, metals exist in different charge states depending on the conditions, and the solvation environment strongly influences their chemistry. Many enzymes have metal ions at their active sites, and electrostatic interactions influence the selectivity for metal ion transport through cell membranes. Metal ions (e.g., Mg+, Ca+) are deposited into the earth's atmosphere by meteor ablation, resulting in a rich variety of atmospheric chemistry. Similarly, metal ions ( Mg+) have been observed in planetary atmospheres and in the impact of the comet Shoemaker-Levy 9 on Jupiter. In various circumstances, the electrostatic interactions of metal ions determine the outcome of significant chemistry. Cluster chemistry has made significant contributions to the understanding of these stronger metal ligand interactions and weaker metal ion solvation interactions. In this volume, the authors explore a variety of work in these general areas, where new cluster science techniques in the gas phase have made it possible to synthesize new kinds of complexes with metals and to measure their properties in detail.

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Atomic & Molecular Clusters
Roy L. Johnston
Manufacturer: CRC
ProductGroup: Book
Binding: Paperback

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ASIN: 0748409319

Book Description

Cluster physics is the foundation of the increasingly important field of nanotechnology. Clusters, ranging in size from a few to many millions of atoms, constitute a fascinating field of research in physics, chemistry and materials science. They are formed by most of the elements of the Periodic Table, and the types of bonding and the resultant clusters are equally as varied. This book introduces atomic clusters, ranging from weakly-bonded clusters of argon to strongly-bonded carbon clusters and metal nano-particles. It includes worked examples to enable lecturers and students to gauge their understanding and progress. Atomic and Molecular Clusters describes the experimental generation, detection and interrogation of clusters and theoretical approaches developed to aid understanding of their physical properties. It classifies clusters according to their bonding types and gives examples of present and possible future applications of clusters in electronic, optical and magnetic devices.

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